Enhanced Corrosion Resistance of Polyvinyl Butyral Coatings with Nanoparticles

Researchers from the University of Tabriz, led by Taher Rabizadeh, have made a groundbreaking discovery in the field of nanotechnology. By incorporating polymethylhydrosiloxane (PMHS) and Mg(OH)2 nanoparticles into polyvinyl butyral (PVB) coatings, they have significantly improved the corrosion resistance of the coatings. The study employed advanced analytical techniques, including SEM, FTIR, EDS, and water contact angle, to assess the properties of the coatings. The findings show that the addition of PMHS and Mg(OH)2 nanoparticles enhanced the hydrophobicity of the PVB matrix, leading to improved corrosion resistance.

Key Takeaways:

  • The study investigated the effects of adding PMHS and Mg(OH)2 nanoparticles on the corrosion resistance of PVB coatings deposited on mild steel by spin coating.
  • The PVB-PMHS coatings produced with 10 v/v%, 20 v/v% PMHS, or 30 v/v% PMHS were crack-free and had a uniform thickness.
  • Increasing the amount of PMHS coating enhanced the hydrophobicity of the PVB matrix, leading to improved corrosion resistance.
  • The corrosion current density decreased from 15.8 μA/cm2 to 0.083 μA/cm2 with the addition of 30 v/v% PMHS.
  • The optimal concentration of PMHS to produce a PVB-PMHS layer with the highest corrosion resistance was found to be 30 v/v%.
  • The addition of 1 g/l Mg(OH)2 nanoparticles increased the corrosion properties of the polymer coating by 2 times.
  • After 7 days of immersion in the corrosive electrolyte, no corrosion products were observed on the surface of the composite coating.

Statistics:

  • The corrosion current density decreased from 15.8 μA/cm2 to 0.083 μA/cm2 with the addition of 30 v/v% PMHS.
  • The corrosion properties of the polymer coating were increased by 2 times with the addition of 1 g/l Mg(OH)2 nanoparticles.
  • The optimal concentration of PMHS to produce a PVB-PMHS layer with the highest corrosion resistance was found to be 30 v/v%.
  • The composite coating was produced by adding 1 g/l Mg(OH)2 nanoparticles to the PVB-PMHS layer.

Sources:

  • Investigating the Effects of Poly(Methylhydrosiloxane) and Mg(Oh) 2 Nanoparticles On the Corrosion Resistance of Polyvinyl Butyral Coatings. Journal of Materials Engineering and Performance, 2025.
  • NewsRx. New Findings from University of Tabriz in the Area of Nanoparticles Reported [Investigating the Effects of Poly(Methylhydrosiloxane) and Mg(Oh) 2 Nanoparticles On the Corrosion Resistance of Polyvinyl Butyral Coatings]. Nanotechnology Weekly. October 27, 2025; p 2028.