Nanocomposite Breakthrough for Efficient Removal of Chromium(VI) and Dyes
Researchers from Prince Sattam bin Abdulaziz University in Saudi Arabia have developed an innovative nanocomposite material that can efficiently remove chromium(VI) and anionic/cationic dyes from industrial wastewater. The new material, called chitosan/carbon/ZnMnO nanocomposite (Cs/C/ZMO), was engineered through a two-step synthesis process and demonstrated exceptional selectivity for Cr(VI) removal over competing cations. This breakthrough has significant implications for the treatment of industrial wastewater and the circular economy.
Key Takeaways:
- The Cs/C/ZMO nanocomposite was engineered through a two-step synthesis process, involving hydrothermal conversion of zinc-carbon battery waste and subsequent chitosan integration via alkaline co-precipitation and epichlorohydrin crosslinking.
- The material exhibited exceptional sorption capacities for Cr(VI), methyl orange, and methylene blue, with removal efficiencies of ~6.565 mmol/g, ~0.621 mmol/g, and ~0.790 mmol/g, respectively.
- The material demonstrated pseudo-first-order kinetics, with equilibrium attained within 50-75 min, and retained ~88% capacity over eight cycles with 90% desorption efficiency.
- The Cs/C/ZMO sorbent exhibited exceptional selectivity for Cr(VI) removal over competing cations in acidic tannery effluent, highlighting its practical utility.
- The research has been peer-reviewed and published in the International Journal of Biological Macromolecules.
Statistics:
- The Cs/C/ZMO nanocomposite exhibited sorption capacities of:
+ ~6.565 mmol/g for Cr(VI) at pH 2.5 and 328 K
+ ~0.621 mmol/g for methyl orange at pH 2.5
+ ~0.790 mmol/g for methylene blue at pH 6.0
- The material retained ~88% capacity over eight cycles with 90% desorption efficiency.
- The equilibrium for Cr(VI) removal was attained within 50-75 min, following pseudo-first-order kinetics.
Sources:
- Chitosan/carbon/ZnMnO nanocomposite for efficient removal of chromium(VI) and anionic/cationic dyes. International Journal of Biological Macromolecules, 2025:146329
- NewsRx. Data on Nanocomposites Detailed by Researchers at Prince Sattam bin Abdulaziz University [Chitosan/carbon/ZnMnO nanocomposite for efficient removal of chromium(VI) and anionic/cationic dyes]. Nanotechnology Weekly. August 18, 2025; p 393.