Novel Biosensing Strategy for Groundwater and Soil Contamination
Researchers at Guizhou University in China have developed a novel biosensing strategy to address the growing problem of groundwater and soil contamination by the organophosphorus pesticide diazinon (DZN). The strategy combines aptamer molecular recognition with surface-enhanced Raman spectroscopy (SERS) to detect diazinon at ultra-low concentrations. This breakthrough has significant implications for the detection and monitoring of environmental pollutants.
Key Takeaways:
- The researchers constructed a SERS biosensing interface with single-molecule detection capability using a high-affinity aptamer and a plasmonic resonance-enhanced substrate.
- The electrochemical surface-enhanced Raman spectroscopy (EC-SERS) method using AgNPs-modified screen-printed electrodes (SPEs) was used for sensitive detection of DZN.
- The detection limit of the sensor for diazinon was up to 5.33 x 10^-12 M, with a good linear response of the characteristic peaks (602 cm) with the concentration of DZN.
- The SERS aptasensor was used to detect diazinon in wastewater and subsurface soil with good recoveries (83.20%-117.78%), which were in good agreement with the results obtained by high-performance liquid chromatography.
- The research demonstrated the sensitivity, stability, and simplicity of operation of the SERS aptasensor, providing a solution for the detection of trace pesticide with ultra-sensitive response and rapid analysis.
- The study concluded that the SERS aptasensor has strong anti-interference capabilities, making it a powerful tool for environmental monitoring.
Statistics:
- Detection limit of the sensor for diazinon: 5.33 x 10^-12 M
- Linear response of the characteristic peaks (602 cm) with the concentration of DZN
- Good recoveries (83.20%-117.78%)
- Good agreement with results obtained by high-performance liquid chromatography
- Sensitivity, stability, and simplicity of operation of the SERS aptasensor
Sources:
- Construction of a silver nanoparticle SERS aptamer-based sensor and its specific recognition of diazinon. Analytical and Bioanalytical Chemistry, 2025.
- Guizhou University, Guiyang, 550025, People's Republic of China
- Springer Heidelberg, Tiergartenstrasse 17, D-69121 Heidelberg, Germany (Publisher: Springer - www.springer.com; Analytical and Bioanalytical Chemistry - www.springerlink.com/content/1618-2642/)
- NewsRx LLC (Our news journalists report that additional information may be obtained by contacting Qian Liu, Guizhou Key Laboratory of Macrocyclic and Supramolecular Chemistry, Guizhou University)